Validation of stm_H2O2_6c_1

Thermodynamic conditions

• Temperature, $T$: 1192.0 K
• Pressure, $p$ : 1.95 atm
• Equivalence Ratio, $\phi$: inf
• Mixture Composition, $X$: 0.22% H2O2-0.07% O2-99.57% AR

Experimental measurement

• Source: experimental data from HCD2010
• Data type: Shock tube measurement
• Experimental method: 0.5 max OH post
• Experimental value: 492.75 $\mu s$
• Experimental uncertainty: $ \times / \div$ 1.51

Model predictions

Trial model prediction: 455.96 $\mu s$

Trial model uncertainty: $ \times / \div$ 1.3

Optimized model prediction: 483.65 $\mu s$

Optimized model uncertainty: $ \times / \div$ 1.1

FFCM-2 performance

Sensitivity and impact factor

Reference

HCD2010 - Hong, Zekai, Cook, R. D., Davidson, D. F., & Hanson, R. K. (2010a). A shock tube study of OH+ H2O2 → H2O+ HO2 and H2O2+ M → 2OH+ M using laser absorption of H2O and OH. The Journal of Physical Chemistry A, 114, 5718–5727.

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