Validation of stm_H2O2_7b_1

Thermodynamic conditions

• Temperature, $T$: 1398.0 K
• Pressure, $p$ : 1.91 atm
• Equivalence Ratio, $\phi$: inf
• Mixture Composition, $X$: 0.25% H2O2-0.06% O2-99.56% AR

Experimental measurement

• Source: experimental data from HCD2010
• Data type: Shock tube measurement
• Experimental method: max OH
• Experimental value: 6.0 $\mu s$
• Experimental uncertainty: $ \times / \div$ 1.23

Model predictions

Trial model prediction: 5.41 $\mu s$

Trial model uncertainty: $ \times / \div$ 1.09

Optimized model prediction: 5.45 $\mu s$

Optimized model uncertainty: $ \times / \div$ 1.05

FFCM-2 performance

Sensitivity and impact factor

Reference

HCD2010 - Hong, Zekai, Cook, R. D., Davidson, D. F., & Hanson, R. K. (2010a). A shock tube study of OH+ H2O2 → H2O+ HO2 and H2O2+ M → 2OH+ M using laser absorption of H2O and OH. The Journal of Physical Chemistry A, 114, 5718–5727.

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