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Performance
That We Know: Validation tests for the base model can be found at the USC-Mech II
website: ·
Species
Profiles in Shock-Tube Oxidation These tests include the
oxidation of H2, CO, CH4, C2H2, C2H4,
C2H6, pC3H4
(propyne), aC3H4
(allene), C3H6, C3H8, 1,3-C4H6
(1,3-butadiene), 1-C4H8 (1-butene), n-C4H10 (n-butane). |
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For higher-hydrocarbons, validation tests include
n-dodecane-air mixtures, p = 1 atm, Tu
= 403 K. You, Egolfopoulos & Wang (2008) Egolfopoulos et al. unpublished (2008) n-pentane, n-hexane & n-heptane-air mixtures, p = 1 atm, Tu = 298 K. Davis & Law (1998). n-Heptane-air mixtures, p = 0.5 to 2 atm, Tu = 350 K. Smallbone et al. (2008). n-Pentane-air mixtures, p = 1, 2, 5 & 10 atm, Tu = 353 K. Kelley & Law. unpublished (2008).
n-dodecane-oxygen-nitrogen,
p5 = 20 atm. Vasu, Davidson, Hong, Vasudevan & Hanson (2008). n-decane-oxygen-argon
and n-heptane-oxygen-argon
mixtures, 1 ≤ p5
≤ 4 atm. Horning,
Davidson & Hanson (2002). n-heptane-oxygen-argon
mixtures, 1 ≤ p5
≤ 2 atm. Smith, Simmie & Curran (2005). n-decane-oxygen-argon
mixtures, p5
= 13 atm. Zhukov, Sechenov, Starikovskii
(2008). n-CkH2k+2 (5 ≤ k ≤ 9)-oxygen-argon mixtures (1.7 ≤ p5 ≤ 5 atm). Davidson & Hanson, unpublished
(2008).
n-decane-oxygen-argon and n-heptane-oxygen-argon
mixtures, p5
= 2 atm. Davidson, Herbon, Horning &
Hanson (2001). n-heptane-oxygen-argon mixtures, (1.61 ≤ p5 ≤ 1.72 atm). Davidson, Oehlschlaeger &
Hanson (2007).
n-dodecane pyrolysis in
jet-stirred reactor (p = 1 atm). Herbinet, Marquaire,
Battin-Leclerc & Fournet (2007). n-dodecane pyrolysis in plug flow
reactor (p = 1 atm). Dahm, Virk, Bounaceur,
Battin-Leclerc, Marquaire, Fournet, Daniau & Bouchez (2004). Kurman, Natelson,
Cernansky & Miller (2009). |